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Global & Regional Environmental Issues

Ozone Depletion & Acid Rain

Stratospheric ozone, ODP, the Montreal Protocol and the chemistry of acid deposition.

PART 1

Topic Breakdown & Traps

The Engineering Principle

Stratospheric ozone shields the surface from harmful UV-B. Chlorofluorocarbons (CFCs), halons and CCl₄ release chlorine/bromine that catalytically destroy ozone; their potency is the Ozone Depletion Potential (ODP), normalised to CFC-11 = 1. The Montreal Protocol phases out these substances. Acid rain forms when SO₂ and NOₓ oxidise to sulphuric and nitric acids, lowering precipitation pH below the natural ≈ 5.6.

The Core Formula Matrix

Ozone Depletion Potential: ODP defined relative to CFC-11 = 1.0.

Montreal Protocol (1987): phases out ozone-depleting substances (ODS).

Natural rain pH ≈ 5.6 (dissolved CO₂ → carbonic acid).

Acid rain precursors: SO₂ → H₂SO₄; NOₓ → HNO₃ (pH < 5.6).

The ‘IIT Traps’

  • ODP is referenced to CFC-11, while GWP is referenced to CO₂ — different baselines.
  • CO₂ is a GHG, not an ozone-depleting substance.
  • Even clean rain is mildly acidic (pH ≈ 5.6) from dissolved CO₂ — acid rain is below that.

📚 Standard references

  • Environmental ChemistryA.K. De · Atmospheric Chemistry
PART 2

Progressive 3-Tier Question Suite

Q1BASIC1 Mark · MCQ
The Ozone Depletion Potential (ODP) of a substance is measured relative to:
Q2MEDIUM1 Mark · MCQ
The international agreement responsible for phasing out ozone-depleting substances is the:
Q3HARD2 Marks · MCQ
Unpolluted rainwater is naturally mildly acidic (pH ≈ 5.6) because of dissolved: